The scc stress corrosion cracking test is meant to evaluate the susceptibility of metallic materials to cracking failure under the combined action of tensile strenght and corrosion in solutions containing hydrogen sulfide h 2 s at high temperatures. Environmentally assisted cracking eac is a general term that includes processes such as stress corrosion cracking scc, hydrogen embrittlement he, sulfide. Stress corrosion cracking scc results from the combined action of three factors. Hydrogen sulfide stress corrosion cracking in materials.
Proof ring is the most simple and affordable loading device. Corrosionpedia what is sulfide stress cracking ssc. Ferritic stainless steels, on the other hand, tend to be fairly resistant to hydrogen stress cracking due to their comparatively low hardness. Sulfide stress corrosion cracking of steels corrosion. In that article, we concluded that while localized corrosion appears to be a prerequisite for anodic eac modes such as stress corrosion cracking scc, hydrogen assisted eac mechanisms like hydrogen stress cracking hsc are exacerbated at cathodic potentials. From the chemical composition point of view, corrosion resistant nickel based alloys are categorized as pure nickel, nickelcopper alloys, nickelmolybdenum alloys, nicrmo alloys and nicrfemo alloys. Large strength alloys such as nickel based alloys are less resistant to sulphide induced stress corrosion cracking when mixed with iron showing that the damages are caused by hydrogen charging the metal while the. Amine corrosion and amine cracking of api 5l x52 carbon steel. Effect of carbon migration on sulfide stress corrosion. Wet h2s corrosion can be a particularly dangerous form of corrosion. The scc of the two steels was attributed to hydrogen embrittlement produced by sulphur and hydrogen sulphide formed by. Carbon steel in anhydrous ammonia can suffer from scc stress corrosion cracking. The observed crack propaga tion is the result of the combined and synergistic interaction of mechanical stress and corrosion re actions. This standard presents metallic material requirements to provide resistance to sulfide stress cracking ssc andor stress corrosion cracking scc for petroleum production, drilling, gathering and flow line equipment, and field processing facilities to be used in hydrogen.
Environmentally assisted cracking eac is a general term that includes processes such as stress corrosion cracking scc, hydrogen embrittlement he, sulfide stress cracking ssc, liquid metal embrittlement lme, and corrosion fatigue cf. However, only scc tests were performed here because industrial experience and an earlier ballot had been successful in demonstrating that ssc and ghsc were not. In this paper, mechanical performance test, slow strain rate test ssrt and optical microscopy analysis were employed in studying the effect of carbon migration on sulfide stress corrosion cracking sscc behaviors of cr5moa3020cr18ni9 dissimilar joints. Sulfide stress cracking an overview sciencedirect topics. Sulfide stress cracning ssc is a form of hydrogen embrittlement which is. Sulfide stress cracking is the cracking of a metal under the combined action of tensile stress and corrosion in the. The major hazards of h 2 s are its ability to cause rapid damage to health or sudden death due to accidental exposure and metal integrity failure due to general corrosion or cracking.
In this research, stress corrosion cracking scc and corrosion behaviour of api 5l x52 carbon steel in 25 wt% diethanolamine solution, saturatedunsaturated with carbon dioxide and containing 0 and 200 ppm hydrogen sulphide at different temperatures were investigated using slow strain rate test, electrochemical measurement and microscopic analysis. Sulfide stress corrosion cracking, also known as sulfide stress cracking ssc, is a stress corrosion cracking phenomena that occurs in the presence of hydrogen sulfide. Hydrogen stress cracking can affect several different types of metals such as high strength structural, carbon, and low alloy steels, along with titanium, nickel, and aluminium alloys. Sulfide stress cracking ssc is a form of hydrogen embrittlement which is a cathodic cracking mechanism. This phenomenon is generally termed sulfide stress cracking ssc when operating at room temperature and stress corrosion cracking scc when operating at.
Stress corrosion cracking the international institute of. The blistering damage tends to form parallel to the. Sour service limits of dualcertified 316316l steel twi. Corrosionpedia what is stress corrosion cracking scc. Hydrogen sulphide gas is a poisonous gas and cannot be emitted into the environment without treatment, thus hydrogen sulphide cracking process has. The anodic and cathodic polarisation curves evidenced the influence of the thiosulphate on the corrosion and the activation effect on the steels. Pdf effect of chloride and sulfate ions on the scc of api. Stress corrosion cracking scc or called as environmentally assisted cracking eac may take place at the electrochemical potential range. Hydrogen sulfide is a colorless, very poisonous, flammable gas with the characteristic foul odor of rotten eggs. This standard addresses the testing of metals for resistance to cracking failure under the combined action of tensile stress and corrosion in aqueous environments containing hydrogen sulfide h 2 s. The most common forms of wet h 2 s cracking are hydrogen induced cracking hic, stress oriented hydrogen induced cracking sohic, and sulfide stress cracking ssc. Hydrogen sulphide cracking is a type atom cracking process that helps in breaking down hydrogen atoms from sulphur atoms in aqueous hydrogen sulphide, which is available in crude oil and natural gas. As a form of hydrogen stress cracking, ssc is a cracking mechanism in pipelines, facilities piping and any equipment.
There are several types of stress corrosion cracking scc, for example, chlorideinduced scc and h 2 sinduced scc. Amine corrosion and amine cracking of api 5l x52 carbon. Laboratory testing of metals for resistance to sulfide. It can lead to unexpected sudden failure of normally ductile metal alloys subjected to a tensile stress, especially at elevated temperature. A corrosive medium especially chloridebearing or hydrogensulphide h2s. This penetration can lead to the brittle fracture of materials that are normally ductile when hydrogen happens to be present in their environment. Sscc is a low temperature temperature where water is liquid effect of h2s in an aqueous environment and. Corrosion testing lab services,hydrogen induced disbonding laboratory,stress corrosion testing lab as per astm,nace standards. This term should not be confused with stress corrosion cracking scs, since this is anodic in nature. Sulfide stress cracking ssc vs hydrogen induced cracking.
The resistance to chlorideinduced stress corrosion cracking of uns n08031 was. This has also been verified by available operating experience. To check its resistance to scc and ssc, several tests were performed. Apart from the classically known hydroxide and nitrate media, stress corrosion cracking of such steels has been reported in a number of other environments, namely aqueous chloride, carbonate, phosphate, ammonia, coco 2h 2 o, high purity water containing oxygen, fuel ethanol and several. Sulphide stress corrosion cracking sulphide stress cracking sscc has special importance in gas and oil industry, as the materials being processed there natural gas and crude oil often contain considerable amount of hydrogen sulphide. Hydrogen sulphide stress corrosion cracking in materials for. Sulphide stress corrosion is a key issue in the petroleum and petrochemical industry because of availability of hydrogen sulphide. Ansinace mr0175hd2003sg metals for sulfide stress cracking. Corrosion testing lab,stress corrosion,materials,hydrogen.
A corrosive medium especially chloridebearing or hydrogensulphide h 2 s media. Element performs sulfide stress cracking ssc testing of metals subject to cracking under the combined action of tensile stress and corrosion in the presence of water and h2s, in compliance with nace tm0177 iso 15156 standards. Final report, phase i, author troiano, a r and hehemann, r f and peterson, j a, abstractnote two point bent beam, nace tensile, cring and dcb stress intensity type specimens were employed to examine a series of steels ssc resistance in the standard nace solution and in. Sulfide stress cracking nace mr01752002, mr0175iso 15156. The specific crystal structure of metals is important, as it affects the rate at which hydrogen can diffuse and deformation mechanisms. Sulfide stress cracking nace mr01752002, mr0175iso. Stress corrosion cracking and hydrogen cracking are two important forms of environmental cracking which can cause serious failures in the oil and gas, pipeline, process and many other industries. As we know that both form of cracking are due to the absorption of atomic hydrogen that is produced by. Stress corrosion cracking international institute of.
Environmental cracking is a general term that includes. Environmental cracking of stainless and nibase alloys hydrogen sulfide corrosion acidic environments. Element performs sulfide stress cracking ssc testing of metals subject to cracking under the combined action of tensile stress and corrosion in the presence. Wet hydrogen sulfide h2s cracking inspectioneering. Wet h 2 s corrosion can be a particularly dangerous form of corrosion because damage caused by it takes place on the interior of. Pdf sulfide stress corrosion cracking and hydrogen induced. This study evaluates the susceptibility to sulphide stress corrosion cracking sscc and hydrogen embrittlement he of api 5lx80 girth welds steel produced in brazil.
Basics of sulfide stress cracking ssc and stress corrosion cracking scc ssc and scc are cracking processes that develop in the presence of water, corrosion and surface tensile stress. Sulfide stress cracking ssc vs hydrogen induced cracking hlc posted in refining, hydrocarbons, oil, and gas. The effects of sulfide stress cracking on the mechanical properties. Stress corrosion cracking of % cr martensitic steels in. This phenomenon is generally termed sulfide stress cracking ssc when operating at room temperature and stress corrosion cracking scc when operating at higher temperatures. Pdf sulfide stress corrosion cracking and hydrogen. In this chapter the terms eac and scc are generally interchangeable. Tests include stress corrosion cracking scc,hydrogen induced cracking test hic, sulfide stress corrosion cracking sscc, intergranular corrosion igc and sulfide stress corrosion cracking sscc at elevated temperature,india,maharashtra,mumbai,bombay,asia. Susceptible alloys, especially steels, react with hydrogen sulfide, forming metal sulfides and atomic hydrogen as corrosion byproducts. Pdf effect of chloride and sulfate ions on the scc of.
Scc is a stress assisted anodic process as a result of synergistic action of ions, such as. It can occur when carbonsteel equipment becomes exposed to wet h 2 s service environments, and it can come in several different forms. In a previous post, we discussed the broad differences between anodic and cathodic forms of environmentally assisted cracking eac. Recommended corrosion resistant alloys for oil and gas wells. Scc is highly chemically specific in that certain alloys are likely to undergo scc only when exposed to a small. Sulfide stress cracking is a form of hydrogen embrittlement that occurs in highstrength steels and in localized hard zones in weldment of susceptible materials.
Stress corrosion cracking scc and sulfide stress cracking ssc are the most common types of corrosion in sour oil and gas. The scc of the two steels was attributed to hydrogen embrittlement produced by sulphur and hydrogen sulphide formed by dismutation and reduction of thiosulphate. Sulfide stress cracking is the cracking of a metal under the combined action of tensile stress and corrosion in the presence of water and hydrogen sulfide a form of hydrogen stress cracking. Pdf stress corrosion cracking and hydrogen cracking. The use of material susceptible to stress corrosion cracking scc. Sulfide stress corrosion cracking and hydrogen induced cracking of a216wcc wellhead flow control valve body article pdf available in case studies in engineering failure analysis. Cormet provides various kinds of loading devices for stress corrosion cracking scc, sulphide stress cracking sscc, hydrogen induced cracking hic, fracture mechanical and fatigue studies. Hydrogen sulfide corrosion and its prevention is an important topic in a range of industrial processes and environments including oil and gas and its related activities. It should not be confused with the term stress corrosion cracking which is an anodic cracking mechanism. Sulfide stress cracking ssc occurs at locations where atomic hydrogen is able to. Critical nominal stress and critical stress intensity factors for sulfide stress corrosion cracking of various steels were determined using fatigueprecracked, laboratory, cantilever beam specimens and short lengths of oil field casing and tubing pressured to failure. Hydrogen sulphide stress corrosion cracking in materials. Sulphide stress corrosion cracking sscc laboratory.
It is a progressive type of failure that produces cracking at stress levels that are well below the materials tensile strength. Stresscorrosion cracking scc is a term used to describe service failures in engineering materials that occur by slow, environmentally induced crack propagation. Stress corrosion cracking scc is characterized by cracks propagating either transgranularly or intergranularly along grain boundaries. Stress corrosion cracking scc is characterized by cracks propagating either. Sulphide stress cracking ssc corrosion in environments containing hydrogen sulphide can cause hydrogen absorption and cracking. Hydrogen stress cracking is a form of hydrogen embrittlement that occurs when corrosion from acids like wet hydrogen sulfide and hydrofluoric acid cause atomic hydrogen to penetrate hardened or higher strength steels and cause stress cracking. Stress corrosion cracking behavior of nickel base alloys. Hydrogen induced cracking hic is a form of tiny blistering damage caused by a high concentration of hydrogen in steel.
Stress corrosion cracking facts and how to reduce the. This test is commonly carried out according to nace tm0177 standard and requires a vessel rated to withstand corrosion and equipped with. This standard presents metallic material requirements to provide resistance to sulfide stress cracking ssc andor stress corrosion cracking scc for petroleum production, drilling, gathering and flow line equipment, and field processing facilities to be used in hydrogen sulfide h2sbearing hydrocarbon service. A corrosive medium especially chloridebearing or hydrogen sulphide h 2 s media. Structural failure due to scc can be very unpredictablefailure could occur after as little as a few hours of exposure, or the equipment could continue to function normally for. Resistance to stress corrosion cracking, laboratory results for springflex sh of constant load specimens loaded to 85 % of the proof strength at the test temperature. Stress corrosion cracking scc is a progressive fracturing that occurs in metals as a result of the combined influence of tensile stress and a corrosive environment. This type of failure is known as stress corrosion cracking, often abbreviated to scc. The results showed that the resistance to sscc of this joint improved first then decline after 98h aging treatments. Stress corrosion cracking facts and how to reduce the risk. Sulfide stress cracking ssc is a type of hydrogen cracking which presents a cathodic embrittlement mechanism. Alloys which are commercially available and those which have modified metallurgical structures and. Stress corrosion cracking scc is the growth of crack formation in a corrosive environment. The test addresses the resistance of metals to cracking failure under the combined action of tensile stress and corrosion in aqueous environments conatining hydrogen sulfide h 2 s.